Hello Freed,
I have reviewed the exported LM25118 Eagle schematic and the pin assignment of the LM25118 Eagle symbol matches the pin assignment of the footprint. But plesae note that the symbol pin assignment is not in sequence. If you use Eagle schematic to generate the ratsnest for PCB, the pin mapping should be fine.
Can you share the Eagle schematic with me and I can double check the pin assignment: howard.chen@ti.com